Synthesis 1988; 1988(4): 318-319
DOI: 10.1055/s-1988-27554
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Preparation of (Trimethylsilyl)methyl Halides and Trifluoromethanesulfonate by Methylene Insertion Using Diazomethane

Jong Gun Lee* , Dong Soo Ha
  • *Department of Chemistry, Pusan National University, Pusan 607, Korea
Further Information

Publication History

Publication Date:
20 August 2002 (online)

(Trimethylsilyl)methyl halides (1,3) and trifluoromethanesulfonate (triflate) (2) were prepared by inserting a methylene group into the siliconheteroatom bond of trimethylsilyl halides and triflate using diazomethane.