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Synthesis 1988; 1988(3): 234-236
DOI: 10.1055/s-1988-27526
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Highly Stereoselective Synthesis of Vinylsilanes from Carbonyl Compounds

José Barluenga* , José L. Fernández-Simón, José M. Concellón, Miguel Yus
  • *Departamento de Química Organometálica, Facultad de Quimica, Universidad de Oviedo, E-33071 Oviedo, Spain
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Publikationsdatum:
20. August 2002 (online)

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The in situ generated (chlorolithiomethyl)trimethylsilane reacts at - 60°C to - 45°C with different aldehydes or ketones 1 to afford, after lithiation with lithium naphthalenide at - 78 °C to 20 °C, vinylsilanes 5a-b in a stereoselective manner.