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Synthesis 1987; 1987(8): 741-742
DOI: 10.1055/s-1987-28071
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Oxidation von sec, sec-1,2-Diolen zu 1,2-Diketonen unter Pfitzner-Moffatt-Bedingungen

Rainer Schobert*
  • *Institut für Organische Chemie der Universität Erlangen - Nürnberg, Henkestraße 42, D-8520 Erlangen, West Germany
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Publication Date:
12 September 2002 (online)

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Oxidation of sec, sec-1,2-Diols to 1,2-Diketones under Pfitzner-Moffatt-Conditions In contrast to many other oxidation methods, the "Pfitzner-Moffatt" technique converts sec, sec-1,2-diols 1 into 1,2-diketones 2 without any C - C bond cleavage. Other functional groups like oletinic double bonds or esters are not affected under the mild and almost neutral reaction conditions.