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Synthesis 1987; 1987(6): 577-578
DOI: 10.1055/s-1987-28012
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A Novel Aromatic Electrophilic Substitution: Acylation of Aromatics with Cyclic Isoimidium Salts to Yield N,N-Disubstituted ß-Aroylcarboxamides

Alexandru R. Balaban* , Theodor-Silviu Balaban, Gerhard V. Boyd
  • *Department of Organic Chemistry, The Polytechnic Institute, Splaiul Independentei, 76206 Bucharest, Rumania
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Publication Date:
20 August 2002 (online)

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Cyclic isoimidium perchlorates derived from N,N-diethylphthalamic acid and the monomorpholides of succinic and maleic acid react with benezene, toluene or anisole in the presence of aluminium chloride to give the corresponding ß-aroylcarboxamides in moderate yields.

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