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Synthesis 1987; 1987(5): 487-489
DOI: 10.1055/s-1987-27978
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A Simple, One-Pot Transformation of t-Alkyl Chlorides Into (t-Alkyl)amines

Anna Koziara* , Krystyna Osowska-Pacewicka, Stefan Zawadzki, Andrzej Zwierzak
  • *Institute of Organic Chemistry, Technical University (Politechnikaj, Żwirki 36, PL-90-924 Łódź 40, Poland
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Publication History

Publication Date:
18 September 2002 (online)

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t-Alkyl chlorides are readily azidated using trimethylsilyl azide in the presence of tin tetrachloride. Tertiary azides can be transformed without isolation into the corresponding (t-alkyl)amine hydrochlorides in a one-pot procedure employing the Staudinger reaction.

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