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Synthesis 1987; 1987(2): 155-156
DOI: 10.1055/s-1987-27868
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Geometric Selectivity of Pig Liver Esterase and its Application to the Separation of Fluorinated Bicyclic Esters

Sames Sicsic* , Jacques Leroy, Claude Wakselman
  • *CNRS-CERCOA, 2, rue Henri Dunant, F-94320 Thiais, France
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Publikationsdatum:
12. September 2002 (online)

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The hydrolysis of exo-2-ethoxycarbonyl-7-oxabicyclo[2.2.1]hept-5-enes 1-3 by pig liver esterase is much faster than that of the endo isomers. This allows an easy separation of an endo - exo mixture on a preparative scale.