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Synthesis 1986; 1986(7): 563-564
DOI: 10.1055/s-1986-31704
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Nickel(0)-catalyzed Reaction of O,O-Dialkyl Phosphonates with Allyl Acetates or Carbonates. A Novel Method of Preparing Allyl Phosphonates

Xiyan Lu* , Jingyang Zhu
  • *Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shanghai 200032, China
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Publication Date:
20 August 2002 (online)

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Allyl phosphonates are synthesized in good yield by the reaction of allyl acetates or carbonates with O,O-dialkyl phosphonates under the catalysis of Ni(cod)2 in the presence of O,N-bis(trimethylsilyl)acetamide(BSA).

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