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Synthesis 1986; 1986(6): 473-474
DOI: 10.1055/s-1986-31677
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Homolytic C-Alkylation of Aldoximes

Attilio Citterio* , Lucio Filippini
  • *Dipartimento di Chimica del Politecnico, Piazza L. da Vinci 32, I-20133 Milano, Italy
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Publication Date:
20 August 2002 (online)

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Thermal decomposition of alkyl peresters in hydrogen donor solvents (cycloalcanes or ethers) in the presence of aldoximes affords (C-l)-alkylated products. The reaction is favored by electron-withdrawing substituents on the oxime and involves free C-radical addition to the imine moiety.

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