Download PDF
Synthesis 1986; 1986(6): 473-474
DOI: 10.1055/s-1986-31677
communication
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Homolytic C-Alkylation of Aldoximes

Attilio Citterio* , Lucio Filippini
  • *Dipartimento di Chimica del Politecnico, Piazza L. da Vinci 32, I-20133 Milano, Italy
Further Information

Publication History

Publication Date:
20 August 2002 (online)

 PDF Download  Permissions and Reprints All articles of this category

Thermal decomposition of alkyl peresters in hydrogen donor solvents (cycloalcanes or ethers) in the presence of aldoximes affords (C-l)-alkylated products. The reaction is favored by electron-withdrawing substituents on the oxime and involves free C-radical addition to the imine moiety.