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Synthesis 1985; 1985(12): 1097-1100
DOI: 10.1055/s-1985-31438
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Barium Hydroxide as Catalyst in Organic Reactions; V. Application in the Horner Reaction under Solid-Liquid Phase-Transfer Conditions

J. V. Sinisterra* , Z. Mouloungui, M. Delmas, A. Gaset
  • *Organic Chemistry Department, Science Faculty, University of Córdoba, Córdoba, Spain
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Publikationsdatum:
27. September 2002 (online)

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A new application of a barium hydroxide catalyst for the Horner reaction is described. The scope of the synthetic method is shown; furthermore, the yields are higher and the reaction times shorter than those previously reported for similar experimental conditions (solid-liquid). Ethyl 3-(1′-pyrenyl)-acrylate and the 3-(1′-pyrenyl)-acrylonitrile are described for the first time.