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Synthesis 1985; 1985(8): 735-738
DOI: 10.1055/s-1985-31328
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Azabicyclic Compounds Synthesis: Reactions of Cyclic β-Enaminoesters with α,β-Unsaturated Carbonyl Compounds

Pascal BRUNERIE* , Jean-Pierre CÉLÉRIER, Michel HUCHÉ, Gérard LHOMMET
  • *Laboratoire de Chimie des Hétérocycles and UA455, Université Pierre et Marie Curie, 4 Place Jussieu, F-75230 Paris, Cedex 05, France
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Publication Date:
17 September 2002 (online)

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Reactions of cyclic β-enaminoesters with α,β-unsaturated acid chlorides or esters have been studied. In all cases, N-acylation takes place and, under certain conditions, a C-alkylation also occurs leading to the formation of azabicyclic products.