Synlett 2021; 32(01): 07-13
DOI: 10.1055/s-0040-1706416
synpacts
© Georg Thieme Verlag Stuttgart · New York

Transition-Metal-Catalyzed Intermolecular C–H Carbonylation toward Amides

Yan-Lin Li
a   State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. of China   Email: jibaoxia@licp.cas.cn
b   University of Chinese Academy of Sciences, Beijing 100049, P. R. of China
,
Zheng-Yang Gu
a   State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. of China   Email: jibaoxia@licp.cas.cn
c   College of Textiles and Clothing and Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Jiangsu, 224003, P. R. of China
,
Ji-Bao Xia
a   State Key Laboratory for Oxo Synthesis and Selective Oxidation, Center for Excellence in Molecular Synthesis, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. of China   Email: jibaoxia@licp.cas.cn
› Author Affiliations
We are grateful for the financial support provided by the NNSFC (21772208), the NSFC of Jiangsu Province (BK20161260), the Key Research Program of Frontier Sciences of CAS (QYZDJSSW-SLH051), and the Joint Open Fund of Jiangsu Collaborative Innovation Center for Ecological Building Materials and Environmental Protection Equipment and Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province (JH201863).
Further Information

Publication History

Received: 02 July 2020

Accepted after revision: 14 July 2020

Publication Date:
17 August 2020 (online)


Abstract

The amide linkage is one of the most important structural moieties in both chemistry and biology. Here, we briefly discuss recent advances in catalytic intermolecular C–H carbonylation reactions for the synthesis of amides, with particular attention to our intermolecular C–H amidation of arenes with carbon monoxide and organic azides to produce amides.

1 Introduction

2 Representative Methods for Amide Synthesis

3 C–H Aminocarbonylation with Carbon Monoxide and Amines

4 C–H Amidation to Amides with Carbon Monoxide and Azides

5 Summary and Outlook

 
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