First Total Synthesis of Artekeiskeanol A, C and Altissimacoumarin D

Anil Talakokkula; Karunakar Baikadi; A. Venkat Narsaiah

doi:10.1055/s-0037-1610873

SynOpen, Inhaltsverzeichnis

CC BY ND NC 4.0 · SynOpen 2019; 03(02): 49-54
DOI: 10.1055/s-0037-1610873

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First Total Synthesis of Artekeiskeanol A, C and Altissimacoumarin D

Anil Talakokkula

,

Karunakar Baikadi

,

A. Venkat Narsaiah*

Organic Synthesis Laboratory, Fluoro-Agrochemicals Department, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, Telangana, India eMail: vnakkirala2001@yahoo.com

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Abstract

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IICT Communication No: IICT/Pubs./2019/066

Abstract

The total syntheses of artekeiskeanol A and C, and altissimacoumarin D have been achieved. The syntheses commenced from commercially available starting materials, 2,4-dihydroxybenzaldehyde and geraniol. The key steps involve Wittig and Riley oxidation reactions.

Keywords

geronyl - scopoletin - isofraxidin - altissimacoumarin - artekeiskeanol

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