Synthesis 2019; 51(06): 1466-1472
DOI: 10.1055/s-0037-1610318
paper
© Georg Thieme Verlag Stuttgart · New York

Selective Semi-Hydrogenation of Terminal Alkynes Promoted by Bimetallic Cu-Pd Nanoparticles

Eduardo Buxaderas
a  Instituto de Química del Sur (INQUISUR-CONICET), Departamento de Química, Universidad Nacional del Sur, Avda. Alem 1253, 8000 Bahía Blanca, Argentina   Email: gradivoy@criba.edu.ar
,
María Alicia Volpe
b  Planta Piloto de Ingeniería Química, PLAPIQUI (CONICET-UNS), Camino La Carrindanga Km 7, CC 717, 8000 Bahía Blanca, Argentina
,
Gabriel Radivoy*
a  Instituto de Química del Sur (INQUISUR-CONICET), Departamento de Química, Universidad Nacional del Sur, Avda. Alem 1253, 8000 Bahía Blanca, Argentina   Email: gradivoy@criba.edu.ar
› Author Affiliations
This work was generously supported by the Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET, PIP-2011-268), Agencia Nacional de Promoción Científica y Tecnológica (ANPCyT, Prest. BID, PICT-2014-2171), and Universidad Nacional del Sur (UNS, PGI 24/Q072) from Argentina.
Further Information

Publication History

Received: 18 September 2018

Accepted after revision: 15 October 2018

Publication Date:
21 November 2018 (eFirst)

Abstract

The selective semi-hydrogenation of terminal alkynes was efficiently performed, under mild reaction conditions (H2 balloon, 110 °C), promoted by a bimetallic nanocatalyst composed of copper and palladium nanoparticles (5:1 weight ratio) supported on mesostructured silica (MCM-48). The Cu-PdNPS@MCM-48 catalyst, which demonstrated to be highly chemoselective towards the alkyne functionality, is readily prepared from commercial materials and can be recovered and reused after thermal treatment followed by reduction under H2 atmosphere.

Supporting Information

 
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