Synthesis 2018; 50(24): 4958-4962
DOI: 10.1055/s-0037-1609915
paper
© Georg Thieme Verlag Stuttgart · New York

One-Pot Synthesis of Tetraazamacrocyclic Complexes from the Arnold Salt

Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland   Email: [email protected]
› Author Affiliations
Financial support from the National Science Centre in Poland (NCN, Grant OPUS No. 2014/13/B/ST5/03727) is gratefully acknowledged.
Further Information

Publication History

Received: 16 April 2018

Accepted after revision: 19 July 2018

Publication Date:
09 August 2018 (online)


Abstract

We present an improved synthesis of bis(hexafluorophosphate) Arnold salt, which is a synthon of triformylmethane. The salt is shown to be a substrate for the one-pot, aqueous synthesis of macro­cyclic tetraiminato complexes of copper(II) and nickel(II). The synthesis of complexes is a major improvement over the original stepwise procedure, and is characterized by short reaction time, ease of product separation, scalability, and high yields.

Supporting Information

 
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