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DOI: 10.1055/s-0036-1591741
Emergence of Stimuli-Controlled Switchable Bifunctional Catalysts
Generous financial support from IISER Bhopal is gratefully acknowledged. S.S. thanks UGC, Govt. of India for senior research fellowship.Publication History
Received: 22 October 2017
Accepted after revision: 20 November 2017
Publication Date:
19 December 2017 (online)
Dedicated to Professor Milko E. van der Boom on the occasion of his 48th birthday
Abstract
Can a single catalyst perform more than one ‘type’ of reaction? If we consider traditional design of catalysts, then the answer would probably be ‘no’. However, with the advancement of catalyst design concepts, chemists have been able to demonstrate the above task, thanks to ‘stimuli-switchable bifunctional catalysts’. Within the nascent research area of ‘artificial switchable catalysis’, this new type of system offers the potential to achieve complex functions which are otherwise difficult or impossible. This Synpacts article highlights the rise of these new-generation catalysts.
1 Introduction
2 Key Advances
3 Conclusion
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References
- 1a Blanco V. Leigh DA. Marcos V. Chem. Soc. Rev. 2015; 44: 5341
- 1b Neilson BM. Bielawski CW. ACS Catal. 2013; 3: 1874
- 1c Teator AJ. Lastovickova DN. Bielawski CW. Chem. Rev. 2016; 116: 1969
- 1d Romanazzi G. Degennaro L. Mastrorilli P. Luisi R. ACS Catal. 2017; 7: 4100
- 1e Yu Z. Hecht S. Chem. Commun. 2016; 52: 6639
- 1f Guillaume SM. Kirillov E. Sarazin Y. Carpentier J.-F. Chem. Eur. J. 2015; 21: 7988
- 1g Wang F. Liu X. Willner I. Angew. Chem. Int. Ed. 2015; 54: 1098
- 1h Schmittel M. Chem. Commun. 2015; 51: 14956
- 1i Lifschitz AM. Rosen MS. McGuirk CM. Mirkin CA. J. Am. Chem. Soc. 2015; 137: 7252
- 1j Göstl R. Senf A. Hecht S. Chem. Soc. Rev. 2014; 43: 1982
- 1k Leibfarth FA. Mattson KM. Fors BP. Collins HA. Hawker CJ. Angew. Chem. Int. Ed. 2013; 52: 199
- 1l Stoll RS. Hecht S. Angew. Chem. Int. Ed. 2010; 49: 5054
- 1m Lüning U. Angew. Chem. Int. Ed. 2012; 51: 8163
- 2a Cheng C. Stoddart JF. ChemPhysChem 2016; 17: 1780
- 2b Stoddart JF. Angew. Chem. Int. Ed. 2017; 56: 11094
- 2c Sauvage J.-P. Angew. Chem. Int. Ed. 2017; 56: 11080
- 2d Feringa BL. Angew. Chem. Int. Ed. 2017; 56: 11060
- 2e Zhang Q. Qu D.-H. ChemPhysChem 2016; 17: 1759
- 2f Erbas-Cakmak S. Leigh DA. McTernan CT. Nussbaumer AL. Chem. Rev. 2015; 115: 10081
- 3 Beswick J. Blanco V. Bo GD. Leigh DA. Lewandowska U. Lewandowski B. Mishiro K. Chem. Sci. 2015; 6: 140
- 4 Kwan C.-S. Chan AS. C. Leung KC.-F. Org. Lett. 2016; 18: 976
- 5 De S. Pramanik S. Schmittel M. Angew. Chem. Int. Ed. 2014; 53: 14255
- 6 Mittal N. Pramanik S. Paul I. De S. Schmittel M. J. Am. Chem. Soc. 2017; 139: 4270
- 7 Biernesser AB. Chiaie KR. D. Curley JB. Byers JA. Angew. Chem. Int. Ed. 2016; 55: 5251
- 8 Treator AJ. Shao H. Lu G. Liu P. Bielawski CW. Organometallics 2017; 36: 490
- 9 Fogg DE. dos Santos EN. Coord. Chem. Rev. 2004; 248: 2365
- 10a Arisawa M. Fuji Y. Kato H. Fukuda H. Matsumoto T. Ito M. Abe H. Ito Y. Shuto S. Angew. Chem. Int. Ed. 2013; 52: 1003
- 10b Aillerie A. Rodriguez-Ruiz V. Carlino R. Bourdreux F. Guillot R. Bezzenine-Lafollée S. Gil R. Prim D. Hannedouche J. ChemCatChem 2016; 8: 2455
- 10c Schmidt B. Krehl S. Jablowski E. Org. Biomol. Chem. 2012; 10: 5119
- 10d Schmidt B. Krehl S. Hauke S. J. Org. Chem. 2013; 78: 5427
- 10e Kato H. Ishigame T. Oshima N. Hoshiya N. Shimawaki K. Arisawa M. Shuto S. Adv. Synth. Catal. 2011; 353: 2676
- 11 Semwal S. Choudhury J. ACS Catal. 2016; 6: 2424
- 12 Semwal S. Choudhury J. Angew. Chem. Int. Ed. 2017; 56: 5556
- 13 Eichstaedt K. Jaramillo-Garcia J. Leigh DA. Marcos V. Pisano S. Singleton TA. J. Am. Chem. Soc. 2017; 139: 9376
- 14 Gaikwad S. Goswami A. De S. Schmittel M. Angew. Chem. Int. Ed. 2016; 55: 10512
For recent reviews on switchable catalysis, see:
For reviews, see: