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Synthesis 2018; 50(06): 1331-1342
DOI: 10.1055/s-0036-1591733
DOI: 10.1055/s-0036-1591733
paper
TiCl4-Mediated Synthesis of 3,4-Hetero-Disubstituted Isocoumarins by Means of Isocyanide Insertion Reactions
This work has been supported by IDEX, referenced as «ANR-10-IDEX-0001-02 PSL.Further Information
Publication History
Received: 11 October 2017
Accepted after revision: 07 November 2017
Publication Date:
13 December 2017 (online)
Abstract
The isocyanide insertion into sulfanyl-phthalides under Lewis acid conditions is reported with full details. This sequential three-component reaction affords a new straightforward and highly convenient method for the preparation of 3-amino-4-sulfanyl isocoumarins, the potential of which is still unexplored.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1591733.
- Supporting Information
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See also:
For reviews on isocyanide insertion reactions, see: