Stereoselective Synthesis of 2,3-Unsaturated Pseudoglycosides Promoted by Ultrasound

Abstract

The ultrasound-promoted glycosidation of several alcohols using 3,4,6-tri-O-acetyl-d-glucal as the glycosyl donor is described. The products were obtained in a short reaction time at room temperature in good yield and α-selectivity in an open flask, thus avoiding the preparation and manipulation of unstable or sensitive catalysts.

Key words

2,3-unsaturated O-glycosides - glycosidation reaction - ultrasound - p-toluenesulfonic acid - 3,4,6-tri-O-acetyl-d-glucal

• References

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