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Synthesis 2016; 48(05): 765-771
DOI: 10.1055/s-0035-1561114
DOI: 10.1055/s-0035-1561114
paper
Synthesis of Decytospolide A, B and Their C-3 Epimers Using Stereoselective Oxypalladation
Further Information
Publication History
Received: 12 November 2015
Accepted after revision: 04 December 2015
Publication Date:
04 January 2016 (online)
Abstract
Stereoselective synthesis of decytospolide A and B and their C-3 epimers, which have a 2,6-cis-tetrahydropyran ring, has been achieved in high stereoselectivity and yield. The oxypalladation of single diastereomers of 6-(benzyloxy)-7-hydroxydodec-2-enyl 2-naphthoates was optimized to give products with a 2,6-cis-tetrahydropyran ring with high diastereoselectivity and yield.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1561113.
- Supporting Information
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For recent reviews of the synthesis of tetrahydropyrans: