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Synthesis 2015; 47(12): 1780-1790
DOI: 10.1055/s-0034-1380383
DOI: 10.1055/s-0034-1380383
paper
Use of Ligand-Free Iron/Copper Cocatalyst for Nitrogen and Sulfur Cross-Coupling Reaction with 6-Iodoimidazo[1,2-a]pyridine
Further Information
Publication History
Received: 11 December 2014
Accepted after revision: 18 February 2015
Publication Date:
21 April 2015 (online)
Abstract
A ligand-free cooperative bimetallic iron/copper catalysis system was found to introduce various azoles and thiols onto 6-iodoimidazo[1,2-a] pyridine. After optimization, the inexpensive, nontoxic, air-stable, and commercially available CuO and FeCl2·4H2O enabled a regioselective N- and S-arylation of common nitrogen heterocycles and of a broad range of mercaptans including aliphatic, aromatic, and heterocyclic thiols.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380383.
- Supporting Information
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