Synlett 2015; 26(01): 73-75
DOI: 10.1055/s-0034-1378936
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© Georg Thieme Verlag Stuttgart · New York

Methyl 4-Pentafluorosulfanylphenyl Sulfoximines

Christine M. M. Hendriks
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany   Fax: +49(241)8092391   Email: carsten.bolm@oc.rwth-aachen.de
,
Jens Reball
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany   Fax: +49(241)8092391   Email: carsten.bolm@oc.rwth-aachen.de
,
Carsten Bolm*
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany   Fax: +49(241)8092391   Email: carsten.bolm@oc.rwth-aachen.de
› Author Affiliations
Further Information

Publication History

Received: 26 September 2014

Accepted after revision: 20 October 2014

Publication Date:
20 November 2014 (online)


Abstract

A low-cost and high-yielding synthetic route towards methyl 4-pentafluorosulfanylphenyl sulfoximines from the corresponding sulfide has been developed. The intermediate N-cyano sulfoximine was converted into the corresponding N-(1H)-tetrazole, and the NH-sulfoximine was modified by N-arylation and N-alkylation reactions.

Supporting Information

 
  • References and Notes


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