Palladium-Catalyzed Interceptive Decarboxylative Addition of Allyl Car­bonates with Carbonyl Group

Abstract

The first palladium-catalyzed interceptive decarboxylative 1,4-addition of allyl carbonates with squarates is reported. Interestingly, the C-3 carbonyl group of N-substituted isatins undergoes smooth decarboxylative 1,2-addition with allyl carbonates. This transformation offers a straightforward method for the synthesis of spiro-oxepane-fused 2-oxindole.

Key words

palladium - allylation - conjugate addition - allyl complexes - spiro compounds - metathesis

• References and Notes

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