An Efficient Synthetic Approach to Substituted Trisphenols (Phloroglucide Analogues) Using Tungstosilicic Acid in Water

Reza Fareghi-Alamdari; Ali Khalafi-Nezhad; Negar Zekri

doi:10.1055/s-0033-1340681

Synthesis, Table of Contents

Synthesis 2014; 46(07): 887-892
DOI: 10.1055/s-0033-1340681

paper

An Efficient Synthetic Approach to Substituted Trisphenols (Phloroglucide Analogues) Using Tungstosilicic Acid in Water

Authors

Reza Fareghi-Alamdari*

^aFaculty of Chemistry & Chemical Engineering, Malek-Ashtar University of Technology, Tehran, Iran Fax: +98(21)22970195 Email: reza_fareghi@yahoo.com
Ali Khalafi-Nezhad

^bCollege of Science, Department of Chemistry, Shiraz University, Shiraz, Iran
Negar Zekri

^aFaculty of Chemistry & Chemical Engineering, Malek-Ashtar University of Technology, Tehran, Iran Fax: +98(21)22970195 Email: reza_fareghi@yahoo.com

Abstract

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Abstract

Tungstosilicic acid was found to be an efficient catalyst for the synthesis of trisphenols using the reaction of 2,6-bis(hydroxymethyl)phenols with phenols in an aqueous medium. The catalytic reactivity of tungstosilicic acid in boiling water was examined with a series of substrates, demonstrating that this catalyst is reactive in the presence of a variety of functionalities.

Key words

tungstosilicic acid - trisphenols - phenols - 2,6-bis(hydroxymethyl)phenols - synthesis

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References

References

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Supplementary Material

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