Synlett 2013; 24(13): 1675-1678
DOI: 10.1055/s-0033-1339277
letter
© Georg Thieme Verlag Stuttgart · New York

Dehydroaromatization with V2O5

Megha Karki, Hugo C. Araujo, Jakob Magolan*
  • Department of Chemistry, University of Idaho, Moscow, ID 83844-2343, USA   Fax: +1(208)8856173   Email: jmagolan@uidaho.edu
Further Information

Publication History

Received: 01 April 2013

Accepted after revision: 24 May 2013

Publication Date:
12 July 2013 (eFirst)

Abstract

Vanadium pentoxide is evaluated as a dehydroaromatization reagent. Tetrahydrocarbazole is readily aromatized by V2O5 in refluxing acetic acid under both stoichiometric and catalytic conditions. Indoline, tetrahydroquinoline, and tetrahydroquinoxaline are effectively aromatized by V2O5/silica in refluxing toluene.

 
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