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Synthesis 2014; 46(05): 607-612
DOI: 10.1055/s-0033-1338578
DOI: 10.1055/s-0033-1338578
paper
Copper/Silver-Mediated Decarboxylative Trifluoromethylation of α,β-Unsaturated Carboxylic Acids with CF3SO2Na
Weitere Informationen
Publikationsverlauf
Received: 18. August 2013
Accepted after revision: 29. November 2013
Publikationsdatum:
17. Dezember 2013 (online)
Abstract
A copper/silver-catalyzed decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids with CF3SO2Na was performed under relatively mild conditions. The reaction shows high E/Z selectivity and wide substrate tolerance. Ag2CO3 plays an important role in promoting the decarboxylation process.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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