Synthesis of Functionalized Indanes via Palladium-Catalyzed Carboannulation of Diazabicyclic Olefins with o-Iodostyrenes

Eliyan Jijy; Praveen Prakash; Shreyass Saranya; Eringathodi Suresh; Kokkuvayil Vasu Radhakrishnan

doi:10.1055/s-0033-1338507

Synthesis, Table of Contents

Synthesis 2013; 45(18): 2583-2592
DOI: 10.1055/s-0033-1338507

paper

Synthesis of Functionalized Indanes via Palladium-Catalyzed Carboannulation of Diazabicyclic Olefins with o-Iodostyrenes

Eliyan Jijy

^aOrganic Chemistry Section of Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Trivandrum 695019, India

,

Praveen Prakash

^aOrganic Chemistry Section of Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Trivandrum 695019, India

,

Shreyass Saranya

^aOrganic Chemistry Section of Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Trivandrum 695019, India

,

Eringathodi Suresh

^bAnalytical Sciences Discipline, Central Salt and Marine Chemicals Research Institute, Bhavnagar, Gujarat 364002, India Fax: +91(471)2491712 Email: radhu2005@gmail.com

,

Kokkuvayil Vasu Radhakrishnan*

^aOrganic Chemistry Section of Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (CSIR), Trivandrum 695019, India

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Abstract

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Abstract

Palladium-catalyzed carboannulation of bicyclic and tricyclic hydrazines with substituted o-iodostyrenes produced functionalized indanes in good to excellent yields. The methodology provides an important carbocyclic ring system under relatively mild conditions.

Key words

palladium - diazabicyclic olefins - carboannulation - o-iodostyrenes - functionalized indanes

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References

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