A Novel Synthesis of Thioglycolurils by Ring Contraction of 5,7-Dialkyl-3-thioxoperhydroimidazo[4,5-e]-1,2,4-triazin-6-ones

Abstract

A new synthetic route to (E)-1,3-dialkyl-4-(benzylid­eneamino)-5-thioxohexahydroimidazo[4,5-d]imidazol-2(1H)-ones (thioglycolurils), by a ring contraction reaction of 5,7-dialkyl-3-thioxoperhydroimidazo[4,5-e]-1,2,4-triazin-6-ones with aromatic aldehydes, has been developed.

Key words

N-heterocycles - thioglycolurils - 3-thioxoperhydroimidazo[4,5-e]-1,2,4-triazin-6-ones - aromatic aldehydes - ring contraction

• References

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