Synlett 2012; 23(13): 1995-1996
DOI: 10.1055/s-0032-1316995
spotlight
© Georg Thieme Verlag Stuttgart · New York

Copper(II) Acetate

Mojtaba Amini
Chemistry Department, Sharif University of Technology, Tehran, P.O. Box 11155-3615, Iran, Email: mojtaba_a214@yahoo.com
› Author Affiliations
Further Information

Publication History

Publication Date:
26 July 2012 (online)

Dedicated to my supervisor Prof. Mojtaba Bagherzadeh.

Introduction

Copper(II) acetate, or cupric acetate, is a dark green crystalline solid with the formula Cu(OAc)2. X-ray measurements indicate that this compound is monoclinic with space group C2/c and unit-cell dimensions a = 13.15, b = 8.52, c = 13.90 Å.[ 1 ]

Copper(II) acetate monohydrate is produced by the reaction of copper(II) carbonate or copper(II) hydroxide with a solution of acetic acid or by the reaction of copper(II) oxide with hot dilute acetic acid. Copper(II) acetate is used as a textile dyeing, ceramic pigment and catalyst in organic reactions.[ 2 ]

 
  • References

  • 1 Niekerk JN. V, Schoening FR. L. Nature 1953; 171: 36
  • 2 Wayne Richardson H. Copper Compounds. In Ullmann’s Encyclopedia of Industrial Chemistry. Wiley-VCH; Weinheim: 2005
  • 3 Gowda RR, Chakraborty D. J. Mol. Catal. A: Chem. 2011; 349: 86
  • 4 Lisboa CS, Santos VG, Vaz BG, Lucas NC, Eberlin MN, Garden SJ. J. Org. Chem. 2011; 76: 5264
  • 5 Zheng H, Zhang Q, Chen J, Liu M, Cheng S, Ding J, Wu H, Su W. J. Org. Chem. 2009; 74: 943
    • 6a Biffis A, Gardan M, Corain B. J. Mol. Catal. A: Chem. 2006; 250: 1
    • 6b Biffis A, Filippi F, Palma G, Lora S, Macca C, Corain B. J. Mol. Catal. A: Chem. 2003; 203: 213
    • 6c Lam PY. S, Bonne D, Vincent G, Clark CG, Combs AP. Tetrahedron Lett. 2003; 44: 1691
    • 6d Evans DA, Katz JL, West TR. Tetrahedron Lett. 1998; 39: 2937
    • 6e Chan DM. T, Monaco KL, Wang R.-P, Winteres MP. Tetrahedron Lett. 1998; 39: 2933
  • 7 Zabawa TP, Kasi D, Chemler SR. J. Am. Chem. Soc. 2005; 127: 11250
  • 8 Sherman ES, Chemler SR, Tan T.-B, Gerlits O. Org. Lett. 2004; 6: 1573