Synthesis of Metallo-Supramolecular Polymers Using 5,5′-Linked Bis(1,10-Phenanthroline) Ligands

Md. Delwar Hossain; Masayoshi Higuchi

doi:10.1055/s-0032-1316858

Synthesis, Table of Contents

Synthesis 2013; 45(6): 753-758
DOI: 10.1055/s-0032-1316858

paper

Synthesis of Metallo-Supramolecular Polymers Using 5,5′-Linked Bis(1,10-Phenanthroline) Ligands

Md. Delwar Hossain

^aElectronic Functional Materials Group, Polymer Materials Unit, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044, Japan

,

Masayoshi Higuchi*

^aElectronic Functional Materials Group, Polymer Materials Unit, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba 305-0044, Japan

^bJST-CREST, Japan Fax: +81(29)8604721 Email: HIGUCHI.Masayoshi@nims.go.jp

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Abstract

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Abstract

5,5′-Linked bis(1,10-phenanthroline)s were synthesized as new bidentate ligands by a palladium-catalyzed Suzuki-type cross-coupling reaction. Coordination of the ligands to Cu(II), Ni(II), Ag(I), and Zn(II) ions resulted in metallo-supramolecular polymer formation. The 1:1 complexation of the ligands and the metal ions was confirmed by UV-vis titration experiments. The high molecular weights of more than 10⁵ Da, caused by the high complexation constants, were confirmed by the SEC-Viscometry-RALLS method.

Key words

bis(1,10-phenanthroline)s - metallo-supramolecular polymers - complexation - cross-coupling - palladium

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References

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