Synthesis 2012; 44(15): 2463-2468
DOI: 10.1055/s-0032-1316541
paper
© Georg Thieme Verlag Stuttgart · New York

Gold-Catalyzed C–H Oxidative Polyacyloxylation Reaction of Hindered Arenes

Alexandre Pradal
a  Chimie ParisTech, Laboratoire Charles Friedel (LCF), 11, rue P. et M. Curie, 75231 Paris cedex 05, France, Fax: +33(1)44071062   Email: patrick-toullec@chimie-paristech.fr   Email: veronique-michelet@chimie-paristech.fr
b  CNRS, UMR 7223, 75231 Paris cedex 05, France
,
Pierre Faudot dit Bel
a  Chimie ParisTech, Laboratoire Charles Friedel (LCF), 11, rue P. et M. Curie, 75231 Paris cedex 05, France, Fax: +33(1)44071062   Email: patrick-toullec@chimie-paristech.fr   Email: veronique-michelet@chimie-paristech.fr
b  CNRS, UMR 7223, 75231 Paris cedex 05, France
,
Patrick Y. Toullec*
a  Chimie ParisTech, Laboratoire Charles Friedel (LCF), 11, rue P. et M. Curie, 75231 Paris cedex 05, France, Fax: +33(1)44071062   Email: patrick-toullec@chimie-paristech.fr   Email: veronique-michelet@chimie-paristech.fr
b  CNRS, UMR 7223, 75231 Paris cedex 05, France
,
Véronique Michelet*
a  Chimie ParisTech, Laboratoire Charles Friedel (LCF), 11, rue P. et M. Curie, 75231 Paris cedex 05, France, Fax: +33(1)44071062   Email: patrick-toullec@chimie-paristech.fr   Email: veronique-michelet@chimie-paristech.fr
b  CNRS, UMR 7223, 75231 Paris cedex 05, France
› Author Affiliations
Further Information

Publication History

Received: 18 April 2012

Accepted: 10 May 2012

Publication Date:
20 June 2012 (online)


Abstract

The synthesis of polyacyloxylated aromatic derivatives was achieved in moderate yields using a gold-catalyzed C–H activation strategy and di(acetoxy)iodobenzene as an oxidant.

 
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