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Synthesis 2012; 44(16): 2515-2518
DOI: 10.1055/s-0031-1290823
DOI: 10.1055/s-0031-1290823
practical synthetic procedures
Convenient Preparation of Long-Chain Dialkyl Phosphates: Synthesis of Dialkyl Phosphates
Authors
Further Information
Publication History
Received: 07 February 2012
Accepted after revision: 02 March 2012
Publication Date:
17 April 2012 (online)
Abstract
Reaction of phosphorus oxychloride with a primary alcohol (1.8 equiv) and triethylamine (1.8 equiv) in toluene, followed by filtration and treatment with steam, gives dialkyl phosphates in good yield and essentially free from trialkyl phosphate contamination.
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