Synthesis of Trifluoroethyl-Substituted Ketones

B. Morandi; E. M. Carreira

doi:10.1055/s-0031-1289355

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Synfacts 2011(12): 1344-1344
DOI: 10.1055/s-0031-1289355

Metal-Mediated Synthesis

Synthesis of Trifluoroethyl-Substituted Ketones

Contributor(s): Paul Knochel, Nadja M. Barl
B. Morandi, E. M. Carreira*
ETH Zürich, Switzerland

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Publication History

Publication Date:
18 November 2011 (online)

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Significance

This work discloses new strategies in aldehyde homologation, accomplished by the reaction of aliphatic and aromatic aldehydes as well as cyclic ketones with in situ generated F₃CCHN₂, furnishing trifluoroethyl-substituted ketones.