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Synfacts 2011(7): 0762-0762
DOI: 10.1055/s-0030-1260637
DOI: 10.1055/s-0030-1260637
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Synthesis of a Chiral Bidentate sp²-N Ligand
K. Miyata, H. Kutsuna, S. Kawakami, M. Kitamura*
Nagoya University, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
17. Juni 2011 (online)
Significance
In this paper the authors describe the preparation of a new family of chiral bidentate sp²-N ligands and demonstrated its utility in a Ru-catalyzed enantioselective dehydrative C-, N-, and O-allylation. Notable is the synthesis of highly enantioslective five- and six-membered cycloalkanes and N- and O-heterocycles - potential key intermediates for biologically active natural products.