Synfacts 2011(7): 0802-0802  
DOI: 10.1055/s-0030-1260592
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Allylation of Aldehydes with Allytributylstannane Using Ti-ZSM-5

Contributor(s): Yasuhiro Uozumi, Takao Osako
B. K. Bhuyan, A. J. Borah, K. K. Senapati, P. Phukan*
Gauhati University, Guwahati, India
Further Information

Publication History

Publication Date:
17 June 2011 (online)

Significance

Titanium-exchanged ZSM-5 (Ti-ZSM-5) was prepared by treatment of ZSM-5 with an aqueous solution of TiCl4 (eq. 1). Ti-ZSM-5 catalyzed the allylation of aldehydes with allyltri­butylstannane to give the corresponding homo­allylic alcohols in 71-85% yield (10 examples, eq. 2).