Allylation of Aldehydes with Allytributylstannane Using Ti-ZSM-5

doi:10.1055/s-0030-1260592

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Synfacts 2011(7): 0802-0802
DOI: 10.1055/s-0030-1260592

Polymer-Supported Synthesis

Allylation of Aldehydes with Allytributylstannane Using Ti-ZSM-5

Contributor(s): Yasuhiro Uozumi, Takao Osako
B. K. Bhuyan, A. J. Borah, K. K. Senapati, P. Phukan*
Gauhati University, Guwahati, India

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Publication History

Publication Date:
17 June 2011 (online)

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Significance

Titanium-exchanged ZSM-5 (Ti-ZSM-5) was prepared by treatment of ZSM-5 with an aqueous solution of TiCl₄ (eq. 1). Ti-ZSM-5 catalyzed the allylation of aldehydes with allyltributylstannane to give the corresponding homoallylic alcohols in 71-85% yield (10 examples, eq. 2).