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Synthesis 2011(14): 2291-2296  
DOI: 10.1055/s-0030-1260070
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

Synthesis of 1,5-Substituted Anthracenes by Means of Kumada Coupling and Their Derivatization

Sebastian Bringmanna, Saleh A. Ahmedb, Ramona Hartmanna, Jochen Mattay*a
a University of Bielefeld, Organic Chemistry I, Universitätsstraße 25, 33615 Bielefeld, Germany
Fax: +49(521)1066146; e-Mail: mattay@uni-bielefeld.de;
b Assuit University, Chemistry Department, Faculty of Science, 71516 Assuit, Egypt
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Publikationsverlauf

Received 4 April 2011
Publikationsdatum:
30. Juni 2011 (online)

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Abstract

Herein, we present a method to access a series of 1,5-functionalized anthracenes through Kumada coupling. All syntheses start from readily available 1,5-dichloroanthracene. The so-formed anthracenes are further derivatized to enable, for example, attachment to supramolecular systems.

Key words

Grignard reaction - Kumada coupling - cross coupling - anthracene - nickel

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Bringmann S., Brodbeck R., Hartmann R., Schäfer C., Mattay J. to be published