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Synfacts 2011(4): 0451-0451  
DOI: 10.1055/s-0030-1259738
Polymer-Supported Synthesis
© Georg Thieme Verlag Stuttgart ˙ New York

Alkylation with Alcohols Catalyzed by Ag/Mo Hybrid Metal

Contributor(s): Yasuhiro Uozumi, Aya Tazawa
X. Cui, Y. Zhang, F. Shi, Y. Deng
Lanzhou Institute of Chemical Physics and Graduate School of Chinese Academy of Sciences, Beijing, P. R. of China
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Publikationsdatum:
18. März 2011 (online)

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Significance

Ag/Mo hybrid metal (Ag-Mo-22) was prepared according to the first equation. The catalyst promoted alkylation of amines, amides, sulfonamides, and ketones with alcohols in the presence of KOt-Bu or K2CO3 to afford the corres-ponding alkylated products in 70 to >99% yield (48 examples).