Suzuki-Miyaura Reaction with a Silica- Supported
Palladium Complex

doi:10.1055/s-0030-1259464

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Synfacts 2011(3): 0340-0340
DOI: 10.1055/s-0030-1259464

Polymer-Supported Synthesis

Suzuki-Miyaura Reaction with a Silica- Supported Palladium Complex

Contributor(s): Yasuhiro Uozumi, Aya Tazawa
W. Chen, P. Li, L. Wang
Huaibei Normal University, Anhui and Shanghai Institute of Organic Chemistry, P. R. of China

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Publikationsdatum:
16. Februar 2011 (online)

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Significance

The silica-supported palladium complex 2 was prepared by mixing phosphine-functionalized silica gel 1 and Pd(OA)₂. The complex 2 catalyzed the Suzuki-Miyaura reaction of aryl boronic acids 3 with aryl halides 4 to afford the corresponding biaryls 5 in up to 94% yield (34 examples).