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Synfacts 2010(12): 1402-1402
DOI: 10.1055/s-0030-1258852
DOI: 10.1055/s-0030-1258852
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New YorkAlkenylative Cross-Coupling between Alkyl Sulfides and Grignard Reagents
K. Ishizuka, H. Seike, T. Hatakeyama, M. Nakamura*
Kyoto University, Japan
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
22. November 2010 (online)
Significance
A novel nickel-catalyzed alkenylative coupling between aryl Grignard reagents and alkyl aryl sulfides was developed. The key feature of this reaction is the use of a bulky NHC ligand (SIPr) that suppresses the conventional biaryl coupling reaction.