A Novel General Phosphine Ligand for Suzuki-Miyaura
Cross-Coupling

W. Tang; A. G. Capacci; X. Wei; W. Li; A. White; N. D. Patel; J. Savoie; J. J. Gao; S. Rodriguez; B. Qu; N. Haddad; B. Z. Lu; D. Krishnamurthy; N. K. Yee; C. H. Senanayake

doi:10.1055/s-0030-1258706

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Synfacts 2010(11): 1285-1285
DOI: 10.1055/s-0030-1258706

Metal-Mediated Synthesis

A Novel General Phosphine Ligand for Suzuki-Miyaura Cross-Coupling

Contributor(s): Paul Knochel, Tobias Thaler
W. Tang*, A. G. Capacci, X. Wei, W. Li, A. White, N. D. Patel, J. Savoie, J. J. Gao, S. Rodriguez, B. Qu, N. Haddad, B. Z. Lu, D. Krishnamurthy, N. K. Yee, C. H. Senanayake
Boehringer Ingelheim Pharmaceuticals Inc., Ridgefield, USA

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Publication History

Publication Date:
21 October 2010 (online)

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Significance

A new class of biaryl monophosphorous ligands with outstanding properties was developed. The ligand BI-DIME is highly air-stable and readily accessible in kilogram scale.