Design and Regioselective Synthesis
of (2-Bromo-2-alkoxycarbonyl)ethyl Acrylates as Inimers for Hyperbranched
(Co)Polyacrylates

Coleen Pugh; Bindu Raveendra; Anirudha Singh; Reichel Samuel; Guillermina Garcia

doi:10.1055/s-0030-1258497

LETTER

Design and Regioselective Synthesis of (2-Bromo-2-alkoxycarbonyl)ethyl Acrylates as Inimers for Hyperbranched (Co)Polyacrylates

Coleen Pugh*, Bindu Raveendra, Anirudha Singh, Reichel Samuel, Guillermina Garcia
The University of Akron, Department of Polymer Science, Maurice Morton Institute of Polymer Science, Akron, OH 44325-3909, USA
Fax: +1(330)9728864; e-Mail: cpugh@uakron.edu;

Abstract

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Abstract

A route based on deaminohalogenation of serine is established to synthesize bromoinimers that can be homopolymerized to produce hyperbranched polyacrylates that are true architectural analogues of linear polyacrylates; that is, an ester group is attached to every other carbon along the polymer backbone, and each repeat unit contains a free ester side chain.

Key words

acrylates - activated ester - deaminohalogenation - inimers - regioselective

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References

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