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Synfacts 2010(7): 0811-0811
DOI: 10.1055/s-0029-1220047
DOI: 10.1055/s-0029-1220047
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Palladium-Catalyzed Oxidative Arylation of ortho-Phenylcarbamates with Arenes
X. Zhao, C. S. Yeung, V. M. Dong*
University of Toronto, Canada
Further Information
Publication History
Publication Date:
22 June 2010 (online)
Significance
A highly useful method for the oxidative palladium-catalyzed coupling of simple arenes and ortho-phenylcarbamates was developed. The reaction proceeds via double C-H bond functionalization with high regioselectivities including electron-rich, -neutral, and -deficient arenes as substrates.