Palladium-Catalyzed Oxidative Arylation of ortho-Phenylcarbamates
with Arenes

doi:10.1055/s-0029-1220047

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Synfacts 2010(7): 0811-0811
DOI: 10.1055/s-0029-1220047

Metal-Mediated Synthesis

Palladium-Catalyzed Oxidative Arylation of ortho-Phenylcarbamates with Arenes

Contributor(s): Paul Knochel, Tobias Thaler
X. Zhao, C. S. Yeung, V. M. Dong*
University of Toronto, Canada

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Publikationsverlauf

Publikationsdatum:
22. Juni 2010 (online)

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Significance

A highly useful method for the oxidative palladium-catalyzed coupling of simple arenes and ortho-phenylcarbamates was developed. The reaction proceeds via double C-H bond functionalization with high regioselectivities including electron-rich, -neutral, and -deficient arenes as substrates.