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Synthesis 2010(10): 1639-1644  
DOI: 10.1055/s-0029-1218724
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

Synthesis of Podands with Cyanurate or Isocyanurate Cores and Terminal Triple Bonds

Flavia Pirona,b, Cornelia Opreaa, Crina Cismaş*a, Anamaria Tereca, Jean Roncalib, Ion Grosu*a
a Babes-Bolyai University, Organic Chemistry Department and CCOCCAN, Cluj-Napoca, 11 Arany Janos str., 400028 Cluj-Napoca, Romania
b University of Angers, CNRS, CIMA, Group Linear Conjugated Systems, 2 Bd Lavoisier, 49045 Angers, France
Fax: +40(264)590818.; e-Mail: csocaci@chem.ubbcluj.ro; e-Mail: igrosu@chem.ubbcluj.ro;
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Publication History

Received 11 February 2010
Publication Date:
06 April 2010 (online)

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Abstract

The synthesis of podands with cyanuric or isocyanuric acid cores and oligoethyleneoxy pendant arms exhibiting terminal triple bonds or brominated triple bonds is reported. The starting material for cyanuric acid derived podands is commercially available cyanuric acid, while the isocyanuric derivatives are obtained by thermal isomerization of the corresponding cyanurates.

Key words

podands - cyanurates - alkynes - isomerization - heterocycles

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