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Synthesis 2009(23): 4075-4081
DOI: 10.1055/s-0029-1217032
DOI: 10.1055/s-0029-1217032
FEATUREARTICLE
© Georg Thieme Verlag
Stuttgart ˙ New YorkPalladium-Catalyzed Cross-Coupling Reaction of AlArEt2(THF) with Aryl Bromides
Further Information
Received
30 July 2009
Publication Date:
12 October 2009 (online)
Publication History
Publication Date:
12 October 2009 (online)
Abstract
Efficient cross-coupling reactions of aryl bromides with AlArEt2(THF) (Ar = Ph, 4-MeC6H4, 4-MeOC6H4, 4-Me3SiC6H4, or 2-naphthyl) catalyzed by a catalytic system of 1 mol% Pd(OAc)2 and 2 mol% PCy3 furnish aryl-aryl coupling products. The system works well for a wide range of aryl bromides regardless of the electronic or steric nature of the substituent on the aryl bromides.
Key words
cross-coupling - palladium - aryl - aluminum - biaryl
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