First Synthesis of 5-Cyanosalicylates
by Formal [3+3] Cyclocondensations of 1,3-Bis(silyloxy)-1,3-butadienes

Abdolmajid Riahi; Olumide Fatunsin; Mohanad Shkoor; Rüdiger Dede; Helmut Reinke; Christine Fischer; Peter Langer

doi:10.1055/s-0028-1088043

PAPER

First Synthesis of 5-Cyanosalicylates by Formal [3+3] Cyclocondensations of 1,3-Bis(silyloxy)-1,3-butadienes

Abdolmajid Riahi^a,b, Olumide Fatunsin^a, Mohanad Shkoor^a, Rüdiger Dede^a, Helmut Reinke^a, Christine Fischer^a,b, Peter Langer*^a,b
^a Institut für Chemie, Universität Rostock, Albert Einstein Str. 3a, 18059 Rostock, Germany
^b Leibniz-Institut für Katalyse, Universität Rostock e.V., Albert Einstein Str. 29a, 18059 Rostock, Germany
Fax: +49(381)4986412; e-Mail: peter.langer@uni-rostock.de;

Abstract

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Abstract

A variety of functionalized benzonitriles were regioselectively prepared by formal [3+3] cyclocondensation of 1,3-bis(silyloxy)-1,3-butadienes with 3-ethoxy- and 3-silyloxy-2-cyano-2-en-1-ones.

Key words

arenes - benzonitriles - cyclizations - regioselectivity - silyl enol ethers

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References

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CCDC-716950 contain all crystallographic details of this publication and is available free of charge at: www.ccdc.cam.ac.uk/conts/retrieving.html or can be ordered from the following address: Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK; Fax: +44(1223)336033, or deposit@ccdc.cam.ac.uk.

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