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DOI: 10.1055/s-0028-1083370
Diastereomeric (η4-diene)Fe(CO)3 Complexes Containing Chiral Amide Groups: A Convenient Method for the Resolution of Amino Acids
Publikationsverlauf
Publikationsdatum:
11. Februar 2009 (online)
Abstract
Diastereomeric (η4-N-substituted-hexa-2,4-dienamide)-Fe(CO)3 complexes bearing chiral amide groups were used for the resolution of (η4-dienecarboxylic acid)Fe(CO)3 complexes. Using the latter, enantiomerically pure proteinogenic or nonproteinogenic α-amino acids were prepared.
Key words
tricarbonyliron complexes - chiral amide groups - resolution - coupling reactions - amino acids
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References
Crystallographic data for compound 10 have been deposited at the Cambridge Crystallographic Data Center (deposition no. CCDC 703290). Copies of these data can be obtained free of charge www.ccdc.cam.ac.uk/data_request/cif.
17Crystallographic data for compound 13 have been deposited at the Cambridge Crystallographic Data Center (deposition no. CCDC 703291). Copies of these data can be obtained free of charge www.ccdc.cam.ac.uk/data_request/cif.