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Synthesis 2008(24): 3931-3936  
DOI: 10.1055/s-0028-1083254
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

A Catalytic Method for Room-Temperature Michael Additions Using 12-Tungstophosphoric Acid as a Reusable Catalyst in Water

Xiang Chena, Jin Shea, Zhicai Shang*a, Jun Wu*a, Peizhi Zhangb
a Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. of China
Fax: +86(571)87952379; e-Mail: shangzc@zju.edu.cn;
b School of Biological and Chemical Engineering, Zhejiang University of Science and Technology, Hangzhou 310012, P. R. of China
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Publication History

Received 18 August 2008
Publication Date:
01 December 2008 (online)

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Abstract

12-Tungstophosphoric acid (H3PW12O40) has been found to be an efficient and recyclable catalyst in promoting room temperature Michael additions of amines and aryl thiols to α,β-unsaturated esters and acrylonitrile in water to afford the corresponding saturated amines in good to excellent yields.

Key words

12-tungstophosphoric acid - Michael addition - α,β-unsaturated ester - acrylonitrile - recyclable catalyst - aqueous medium

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