Synthesis and Investigation of Novel Nickel-based Metal Organic Frameworks

Diandra M. Gheorghe; Anca G. Mirea; Iuliana M. Chirică; Augustin M. Mădălan; Codruţa C. Popescu; Mihaela Matache; Dragoș M. Ciuparu; Mihaela Florea

doi:10.1055/a-2720-5058

Synthesis, Inhaltsverzeichnis

Synthesis
DOI: 10.1055/a-2720-5058

Paper

Published as part of the Special Topic Romanian Chemists in Synthesis

Synthesis and Investigation of Novel Nickel-based Metal Organic Frameworks

Autoren

Diandra M. Gheorghe‡

¹Petroleum Refining Engineering and Environmental Protection Department, Petroleum-Gas University of Ploieşti, Ploieşti, Romania (Ringgold ID: RIN112980)
Anca G. Mirea‡

²Catalytic Materials and Catalysis Laboratory (MATCA), National Institute of Materials Physics, Măgurele, Romania (Ringgold ID: RIN198818)
Iuliana M. Chirică

²Catalytic Materials and Catalysis Laboratory (MATCA), National Institute of Materials Physics, Măgurele, Romania (Ringgold ID: RIN198818)
Augustin M. Mădălan

³Department of Inorganic Chemistry, Organic Chemistry, Biochemistry and Catalysis, University of Bucharest, Faculty of Chemistry, Bucharest, Romania (Ringgold ID: RIN61783)
Codruţa C. Popescu

⁴Research Centre of Applied Organic Chemistry, University of Bucharest, Faculty of Chemistry, Bucharest, Romania (Ringgold ID: RIN61783)
Mihaela Matache

⁴Research Centre of Applied Organic Chemistry, University of Bucharest, Faculty of Chemistry, Bucharest, Romania (Ringgold ID: RIN61783)
Dragoș M. Ciuparu

¹Petroleum Refining Engineering and Environmental Protection Department, Petroleum-Gas University of Ploieşti, Ploieşti, Romania (Ringgold ID: RIN112980)
Mihaela Florea

²Catalytic Materials and Catalysis Laboratory (MATCA), National Institute of Materials Physics, Măgurele, Romania (Ringgold ID: RIN198818)

Abstract

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Abstract

Metal-organic frameworks (MOFs) represent a versatile and highly tunable class of porous coordination polymers. Herein, we present the synthesis of novel MOFs using different synthetic methodologies based on a quionoxaline-multifunctional flexible ligand and nickel ions. The organic ligand was prepared via aromatic nucleophilic substitution using 2,3-dichloroquinoxaline, and its structure and purity were confirmed by NMR spectroscopy. The successful formation of the MOFs was validated by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and FTIR spectroscopy. The thermogravimetry revealed that these new materials are stable below 350 °C, and the analysis of the N₂ adsorption–desorption isotherms confirmed the porous structure. Furthermore, the CO₂ adsorption capacity at room temperature demonstrated that these materials have promising potential for carbon capture and mitigation applications.

Keywords

Metal-organic frameworks - Coordination polymer - Quinoxaline - Multifunctional ligand - Nickel ions - CO₂ adsorption

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Referenzen

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