DOI: 10.1055/s-00000084

Synthesis

eFirst

Publication Date: 18 May 2018

review

Larson, Gerald L.: Some Aspects of the Chemistry of Alkynylsilanes
https://www.thieme-connect.de/media/synthesis/EFirst/i_e0053_ga_10-1055_s-0036-1591979.gif

special topic

Yamaguchi, Eiji; Kamito, Yuji; Matsuo, Kazuki; Ishihara, Jun; Itoh, Akichika: Photooxidative Keto-Trifluoromethylation of Styrenes by Means of an Anthraquinone-Based Organocatalyst
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0116_ga_10-1055_s-0036-1592003.gif
Supporting Information

Publication Date: 17 May 2018

feature

Al-Jawaheri, Yassir; Turner, Matthew; Kimber, Marc C.: Enabling the Rearrangement of Unactivated Allenes to 1,3-Dienes by Use of a Palladium (0)/Boric Acid System
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0138_ga_10-1055_s-0036-1591580.gif
Supporting Information

short review

da Silva, Amanda F.; Fernandes, Alessandra A. G.; Thurow, Samuel; Stivanin, Mateus L.; Jurberg, Igor D.: Isoxazol-5-ones as Strategic Building Blocks in Organic Synthesis
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0102_ga_10-1055_s-0036-1589534.gif

special topic

Wertjes, William; Ayers, Sloan; Gao, Qi; Simmons, Eric M.; Beutner, Gregory L.: A Divergent Nickel-Catalyzed Synthesis of Quinazolinediones and Benzoxazinone Imines
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0192_ga_10-1055_s-0037-1610140.gif
Supporting Information

Publication Date: 16 May 2018

paper

Rasheed, Omer K.; Quayle, Peter: Azo Dyes: New Palladium- and Copper-Catalysed Coupling Reactions on an Old Template
https://www.thieme-connect.de/media/synthesis/EFirst/i_m0072_ga_10-1055_s-0036-1591571.gif
Supporting Information

special topic

Mei, Chong; Hu, Yixin; Lu, Wenjun: Visible-Light-Driven Oxidation of N-Alkylamides to Imides Using Oxone/H2O and Catalytic KBr
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0114_ga_10-1055_s-0036-1591575.gif
Supporting Information

Publication Date: 15 May 2018

feature

Yamashita, Yu; Hirano, Yoichi; Takada, Akiomi; Takikawa, Hiroshi; Suzuki, Keisuke: Total Synthesis of Bis-anthraquinone Antibiotic BE-43472B
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0170_ga_10-1055_s-0037-1610136.jpg
Supporting Information

short review

Bergman, Jan: Comparison of Two Reagents for Thionations
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0082_ga_10-1055_s-0036-1591989.gif

short review

Kirupakaran, Sujenth; Korth, Hans-Gert; Hirschhäuser, Christoph: A Complementary Toolbox of Iterative Methods for the Stereo­selective Synthesis of Heteroatom-Rich Motives from C1-Building Blocks
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0079_ga_10-1055_s-0036-1591996.gif
Supporting Information

Publication Date: 14 May 2018

paper

Cheng, Jiaxin; Yang, Ze; Li, Yuansheng; Xi, Yulan; Sun, Qiu; He, Ling: Synthesis of Isoxazolines and Isoxazoles via Metal-Free Desulfitative Cyclization
https://www.thieme-connect.de/media/synthesis/EFirst/i_f0062_ga_10-1055_s-0037-1609480.gif

paper

Ma, Xinyuan; Huang, Hongtai; Yang, Jianhua; Feng, Xuepu; Xie, Kai: Palladium-Catalyzed Decarboxylative N-3-ortho-C–H Acylation of 1,4-Disubstituted 1,2,3-Triazoles with α-Oxocarboxylic Acids
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0024_ga_10-1055_s-0037-1609729.gif
Supporting Information

special topic

Baumann, Andreas N.; Eisold, Michael; Music, Arif; Didier, Dorian: One-Pot Preparation of Stable Organoboronate Reagents for the Functionalization of Unsaturated Four- and Five-Membered Carbo­- and Heterocycles
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0107_ga_10-1055_s-0036-1592004.gif
Supporting Information

Publication Date: 08 May 2018

paper

Ma, Dengke; Duan, Xinyu; Fu, Chunling; Huang, Xin; Ma, Shengming: Dimethylprolinol Versus Diphenylprolinol in CuBr2-Catalyzed Enantioselective Allenylation of Terminal Alkynols
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0108_ga_10-1055_s-0036-1592007.gif
Supporting Information

paper

Wu, Guang-Long; Wu, Qin-Pei: A Mild Multi-Component Reaction for the Synthesis of 4,5-Disubstituted 1H-1,2,3-Triazoles from Phosphonium Salts, Aldehydes, and Sodium Azide
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0049_ga_10-1055_s-0037-1609720.gif
Supporting Information

paper

Zhu, Zhongxiang; Wang, Qinghe; Kong, Dulin; Huang, Tiao; Wu, Mingshu: CuI-Catalyzed [3+2] Cycloaddition of Hindered Vinylidenebisphosphonates (VBP) with Azomethine Imines for Highly Regioselective Access to Dinitrogen-Heterobicycle-Containing Bisphosphonates
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0800_ga_10-1055_s-0036-1591555.gif
Supporting Information

special topic

Denizot, Natacha; Guillot, Régis; Kouklovsky, Cyrille; Vincent, Guillaume: N-Iodosuccinimide-Mediated Oxidative Coupling of Indoles and Phenols: A Synthetic Study toward the Benzofuroindoline Moiety of Bipleiophylline
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0092_ga_10-1055_s-0036-1592002.gif
Supporting Information CIF File

special topic

Wu, Kui; Fang, Cheng; Kaur, Sarbjeet; Liu, Peng; Wang, Ting: Methylene Blue-Catalyzed Oxidative Cleavage of N-Carbonylated Indoles
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0126_ga_10-1055_s-0036-1592006.gif
Supporting Information

special topic

Zhao, Xinxin; Chen, Ming; Huang, Binbin; Yang, Chao; Gao, Yuan; Xia, Wujiong: Photoinduced Cross-Coupling of Amines with 1,2-Diiodobenzene and Its Application in the Synthesis of Carbazoles
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0084_ga_10-1055_s-0037-1609444.gif
Supporting Information

Publication Date: 03 May 2018

paper

Schmidt, Elena Yu.; Bidusenko, Ivan A.; Ushakov, Igor A.; Protsuk, Nadezhda I.; Trofimov, Boris A.: An Easy Access to Sulfur Derivatives of 6,8-Dioxabicyclo[3.2.1]octanes, Naturally Abundant Scaffolds
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0052_ga_10-1055_s-0036-1591990.gif
Supporting Information

paper

Zhao, Long; Li, Sun; Wang, Lei; Yu, Shun; Raabe, Gerhard; Enders, Dieter: Asymmetric Synthesis of Cyclopentene-Fused Tetrahydroquinolines via N-Heterocyclic Carbene Catalyzed Domino Reactions
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0203_ga_10-1055_s-0036-1591995.gif
Supporting Information

special topic

Garlets, Zachary J.; Wolfe, John P.: Asymmetric Synthesis of Six-Membered Cyclic Sulfamides via Palladium-Catalyzed Alkene Carboamination Reactions
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0078_ga_10-1055_s-0036-1591574.gif
Supporting Information

Publication Date: 25 April 2018

paper

Guo, Yongbiao; Gao, Zhenhua; Fan, Chongxu; Chen, Jisheng; Li, Junchen; Huang, Yongpeng; Huang, Guilan; Yu, Huilan; Zou, Chuanpin: Enantioselective Biginelli Reaction of Aliphatic Aldehydes Catalyzed by a Chiral Phosphoric Acid: A Key Step in the Synthesis of the Bicyclic Guanidine Core of Crambescin A and Batzelladine A
https://www.thieme-connect.de/media/synthesis/EFirst/i_f0091_ga_10-1055_s-0036-1591567.gif
Supporting Information

paper

Liu, Si-Jia; Jiang, Xiao-Li; Wu, Shu-Fang; Tu, Man-Su; Mei, Guang-Jian; Shi, Feng: Efficient Synthesis of Chromenes from Vinyl o-Quinone Methides via a Brønsted Acid Catalyzed Electrocyclization Process
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0061_ga_10-1055_s-0037-1609483.gif
Supporting Information

special topic

Wang, Guang-Zu; Shang, Rui; Fu, Yao: Irradiation-Induced Palladium-Catalyzed Direct C–H Alkylation of Heteroarenes with Tertiary and Secondary Alkyl Bromides
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0136_ga_10-1055_s-0036-1592000.gif
Supporting Information

Publication Date: 24 April 2018

paper

Ding, Rui; Lan, Liyuan; Li, Shuhui; Liu, Yongguo; Yang, Shaoxiang; Tian, Hongyu; Sun, Baoguo: A Novel Method for the Chlorolactonization of Alkenoic Acids Using Diphenyl Sulfoxide/Oxalyl Chloride
https://www.thieme-connect.de/media/synthesis/EFirst/i_f0129_ga_10-1055_s-0037-1609687.gif
Supporting Information

paper

Khalymbadzha, Igor A.; Fatykhov, Ramil F.; Chupakhin, Oleg N.; Charushin, Valery N.; Tseitler, Tatiana A.; Sharapov, Ainur D.; Inytina, Anna K.; Kartsev, Victor G.: Transition-Metal-Free С–С Coupling of 5,7-Dihydroxybenzopyrones with Quinoxalones and Pteridinones
https://www.thieme-connect.de/media/synthesis/EFirst/i_t0135_ga_10-1055_s-0037-1609482.gif
Supporting Information

paper

Khoumeri, Omar; Terme, Thierry; Vanelle, Patrice: First TDAE Reactivity Using Benzonitrile Derivatives as Substrates and Its Application to the Synthesis of 3-Substituted Isochroman-1-ones
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0051_ga_10-1055_s-0036-1591570.gif

paper

Yuan, Jia-Ni; Liu, Hui-Xia; Tian, Qin-Qin; Ji, Nan; Shen, Kuo; He, Wei: Highly Enantioselective Michael Addition of Dithiomalonates to Nitroolefins Catalyzed by New Bifunctional Chiral Thioureas
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0032_ga_10-1055_s-0036-1591987.jpg
Supporting Information

special topic

Du, Yuliu; Wei, Zheng; Wang, Ting: Visible-Light-Mediated Synthesis of Oxidized Amides via Organic Photoredox Catalysis
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0144_ga_10-1055_s-0036-1591988.gif
Supporting Information

special topic

Manick, Anne-Doriane; Tanaka, Hirotaka; Oisaki, Kounosuke; Kanai, Motomu: Organophotoredox/Copper Hybrid Catalysis for Regioselective Allylic­ Aminodecarboxylation of β,γ-Unsaturated Carboxylic Acids
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0125_ga_10-1055_s-0036-1591983.gif
Supporting Information

Publication Date: 19 April 2018

paper

Brütting, Christian; Schmidt, Arndt W.; Kataeva, Olga; Knölker, Hans-Joachim: First Total Synthesis of 7-Isovaleryloxy-8-methoxygirinimbine
https://www.thieme-connect.de/media/synthesis/EFirst/i_t0123_ga_10-1055_s-0037-1609717.gif
Supporting Information

special topic

De, Pinaki Bhusan; Pradhan, Sourav; Shah, Tariq A.; Punniyamurthy, Tharmalingam: Iodine-Mediated Intramolecular C–H Amination of Benzimidazoles: A Metal-Free Route to Dihydroimidazobenzimidazoles
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0140_ga_10-1055_s-0036-1591568.gif
Supporting Information

special topic

Luo, Kai; Zhang, Ling; Wei, Kai; Yang, Wen-Chao; Wu, Lei: Latent Radical Cleavage of α-Allenylic C–O Bonds: Potassium Persulfate Mediated Thiolation of Allenylphosphine Oxides
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0085_ga_10-1055_s-0037-1609835.gif
Supporting Information

Publication Date: 18 April 2018

paper

Hausherr, Arndt; Reissig, Hans-Ulrich: Preparation of 3-Alkyl-Substituted 1-Alkoxyallenes – Synthetic and Mechanistic Aspects
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0195_ga_10-1055_s-0037-1609688.gif
Supporting Information

Publication Date: 16 April 2018

paper

Zheng, Xiaojun; Deng, Qifu; Hou, Qinglin; Zhang, Kaiqiang; Wen, Pushan; Hu, Shunqin; Wang, Haifei: A Chiral Secondary Amine–Amidophosphane Precatalyst for Silver-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition Reactions
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0807_ga_10-1055_s-0037-1609492.gif
Supporting Information

special topic

Deng, Weili; Li, Yajun; Li, You-Gui; Bao, Hongli: Iron-Catalyzed Carboiodination of Alkynes
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0057_ga_10-1055_s-0037-1609448.gif
Supporting Information

special topic

Yin, Zhiping; Power, Dennis J.; Wang, Zechao; Stewart, Scott G.; Wu, Xiao-Feng: Synthesis of 1,3,4-Oxadiazoles via Annulation of Hydrazides and Benzene-1,3,5-triyl Triformate under Metal-Free Conditions
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0837_ga_10-1055_s-0037-1609481.gif
Supporting Information

Publication Date: 12 April 2018

paper

Omlid, Sara M.; Isor, Ankita; Sulkowski, Kathryn L.; Chintala, S. M.; Petroff, John T.; McCulla, Ryan D.: Synthesis of Aromatic Disulfonic Acids for Water-Soluble Dibenzo­thiophene Derivatives
https://www.thieme-connect.de/media/synthesis/EFirst/i_m0035_ga_10-1055_s-0036-1591969.gif
Supporting Information

Publication Date: 04 April 2018

paper

Dong, Jun; Xu, Jiaxi: Safe and Metal-Free Synthesis of 1-Alkenyl Aryl Sulfides and Their Sulfones from Thiiranes and Diaryliodonium Salts
https://www.thieme-connect.de/media/synthesis/EFirst/i_h0042_ga_10-1055_s-0036-1591559.jpg
Supporting Information

paper

Noikham, Medena; Kittikool, Tanakorn; Yotphan, Sirilata: Iodine-Catalyzed Oxidative Cross-Dehydrogenative Coupling of Quinoxalinones and Indoles: Synthesis of 3-(Indol-2-yl)quinoxalin-2-one under Mild and Ambient Conditions
https://www.thieme-connect.de/media/synthesis/EFirst/i_f0047_ga_10-1055_s-0037-1609445.gif
Supporting Information

special topic

Otomura, Nobutaka; Okugawa, Yuto; Hirano, Koji; Miura, Masahiro: Bromine Cation Initiated vic-Diphosphination of Styrenes with Diphosphines under Photoredox Catalysis
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0036_ga_10-1055_s-0037-1609447.gif
Supporting Information

Publication Date: 28 March 2018

paper

Li, Longji; Yang, Qi; Jia, Zongbin; Luo, Sanzhong: Organocatalytic Electrochemical C–H Lactonization of Aromatic Carboxylic Acids
https://www.thieme-connect.de/media/synthesis/EFirst/i_c0030_ga_10-1055_s-0036-1591558.gif
Supporting Information

Publication Date: 27 March 2018

paper

Zens, Anna; Seubert, Philipp; Kolb, Benedikt; Wurster, Marius; Holzwarth, Marcel; Mannchen, Fabian; Forschner, Robert; Claasen, Birgit; Kunz, Doris; Laschat, Sabine: Synthesis of 1-Acyl-2-vinylcyclopropanes: Utilizing Copper-Carbenoid versus Sulfur Ylide Methodology
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0818_ga_10-1055_s-0036-1591554.gif
Supporting Information

short review

Smith, Keith; Alshammari, Mohammed B.; El-Hiti, Gamal A.: Unravelling Factors Affecting Directed Lithiation of Acylamino­aromatics
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0090_ga_10-1055_s-0036-1591954.gif

Publication Date: 08 March 2018

short review

Brikci-Nigassa, Nahida Mokhtari; Bentabed-Ababsa, Ghenia; Erb, William; Mongin, Florence: In Situ ‘Trans-Metal Trapping’: An Efficient Way to Extend the Scope of Aromatic Deprotometalation
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0075_ga_10-1055_s-0036-1591953.gif

Publication Date: 15 February 2018

errata

Denizot, Natacha; Lachkar, David; Kouklovsky, Cyrille; Poupon, Erwan; Evanno, Laurent; Vincent, Guillaume: Divergent Oxidative Couplings between Indoles and 2,3-Dihydroxybenzoic Acid Derivatives for the Biomimetic Synthesis of Voacalgine A and Bipleiophylline

Publication Date: 06 February 2018

feature

Denizot, Natacha; Lachkar, David; Kouklovsky, Cyrille; Poupon, Erwan; Evanno, Laurent; Vincent, Guillaume: Divergent Oxidative Couplings between Indoles and 2,3-Dihydroxybenzoic Acid Derivatives for the Biomimetic Synthesis of Voacalgine A and Bipleiophylline
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0795_ga_10-1055_s-0036-1591910.gif
Supporting Information

Publication Date: 13 December 2017

feature

Kutsumura, Noriki; Okada, Takahiro; Imaide, Satomi; Fujii, Hideaki; Nagase, Hiroshi: Acetic Anhydride Mediated Retro-Ene Reaction via a [4.4.3]Propel­lane Skeleton Intermediate Containing a Quaternary Ammonium Linkage
https://www.thieme-connect.de/media/synthesis/EFirst/i_z0680_ga_10-1055_s-0036-1589138.gif
Supporting Information