Experimental electrochemical potentials of iodine(III) reagents

Felix Debbeler; Daniel Jenisch; Charafa Souilah; Paul Moths; Sergei I. Ivlev; Alicia Casitas

doi:10.1055/a-2650-7789

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Synthesis
DOI: 10.1055/a-2650-7789

paper

Experimental electrochemical potentials of iodine(III) reagents

Felix Debbeler

¹Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany (Ringgold ID: RIN9377)

,

Daniel Jenisch

¹Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany (Ringgold ID: RIN9377)

,

Charafa Souilah

¹Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany (Ringgold ID: RIN9377)

,

Paul Moths

¹Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany (Ringgold ID: RIN9377)

,

Sergei I. Ivlev

²Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany

,

Alicia Casitas

³Fachereich Chemie, Philipps-Universität Marburg, Marburg, Germany (Ringgold ID: RIN9377)

› Author Affiliations
Supported by: Deutsche Forschungsgemeinschaft (DFG) CA 3451/1-1

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We report the electrochemical reduction potentials of a library of 50 iodine(III) reagents, including cyclic alkynyl-, vinyl-, aryl-, cyano-, trifluoromethyl- and azidobenziodoxol(on)es and several linear iodonium salts, which are measured by cyclic voltammetry in acetonitrile and tetrahydrofuran as solvents.

Publication History

Received: 25 April 2025

Accepted after revision: 07 July 2025

Accepted Manuscript online:
07 July 2025

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