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Synlett
DOI: 10.1055/a-2603-8157
letter

Famous but unknown – structural characterization of the Ru-MACHO catalyst

Mike Steffen Bernhard Jørgensen
1   DTU Chemistry, Technical University of Denmark, Lyngby, Denmark (Ringgold ID: RIN5205)
,
Kasper Enemark-Rasmussen
1   DTU Chemistry, Technical University of Denmark, Lyngby, Denmark (Ringgold ID: RIN5205)
,
Mariusz Grzegorz Kubus
1   DTU Chemistry, Technical University of Denmark, Lyngby, Denmark (Ringgold ID: RIN5205)
,
René Wugt Larsen
1   DTU Chemistry, Technical University of Denmark, Lyngby, Denmark (Ringgold ID: RIN5205)
,
Martin Nielsen 
1   DTU Chemistry, Technical University of Denmark, Lyngby, Denmark (Ringgold ID: RIN5205)
› Author AffiliationsSupported by: Villum Fonden 19049
Supported by: Danmarks Frie Forskningsfond 1127-00172B
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Abstract In this work, we present the determination of the crystal structure of the wildly used transition metal complex known as ruthenium macho. The crystal structure of the selectively formed product of the reaction between the titled complex and hydrochloric acid chloroform is also evaluated. The structures determined in this work are compared and evaluated with various spectroscopic techniques.



Publication History

Received: 28 March 2025

Accepted after revision: 08 May 2025

Accepted Manuscript online:
08 May 2025

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